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・ Anthranilate adenylyltransferase
・ Anthranilate hydroxylase
・ Anthranilate N-benzoyltransferase
・ Anthranilate N-malonyltransferase
・ Anthranilate N-methyltransferase
・ Anthranilate phosphoribosyltransferase
・ Anthranilate synthase
・ Anthranilate-based insect repellents
・ Anthranilate—CoA ligase
・ Anthranilic acid
・ Anthranilic acid hydroxylase
・ Anthranilic hydroxylase
・ Anthraniloyl-CoA monooxygenase
・ Anthrapurpurin
・ Anthraquinone
Anthraquinone process
・ Anthraquinones
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Anthraquinone process : ウィキペディア英語版
Anthraquinone process
The anthraquinone process is a process for the production of hydrogen peroxide, which was developed by BASF. The industrial production of hydrogen peroxide is based on the reduction of oxygen, as in the direct synthesis from the elements. Instead of hydrogen itself, however, a 2-alkyl-anthrahydroquinone, which is generated before from the corresponding 2-alkyl-anthraquinone by catalytic hydrogenation with palladium. Oxygen and the organic phase react under formation of the anthraquinone and hydrogen peroxide. Among other alkyl groups (R) ethyl- and tert. Butyl are used, e.g., 2-ethylanthraquinone.〔
〕〔Römpp CD 2006, Georg Thieme Verlag 2006〕
The hydrogen peroxide is then extracted with water and in a second step separated by fractional distillation from the water. The hydrogen peroxide accumulates as sump product. The anthraquinone acts as a catalyst, the overall reaction equation is therefore:
: + →
If ozone is used instead of oxygen, dihydrogen trioxide can be produced by this method.
== References ==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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